Synthesis of Functionalized Diorganyl Selenides from Selenium Dihalides and Allylic Aromatic Compounds
- Authors: Musalov M.V.1, Yakimov V.A.1, Potapov V.A.1, Amosova S.V.1, Zinchenko S.V.1
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Affiliations:
- Favorskii Irkutsk Institute of Chemistry, SB, RAS
- Issue: Vol 55, No 8 (2019)
- Pages: 1153-1159
- Section: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/221052
- DOI: https://doi.org/10.1134/S1070428019080141
- ID: 221052
Cite item
Abstract
Hitherto unknown addition and methoxyselenation reactions of selenium dihalides with methyl eugenol and allyl naphth-1-yl ether were studied. The addition and methoxyselenation reactions of selenium dihalides with methyl eugenol led mainly to Markovnikov products, while the formation of anti-Markovnikov products prevailed in the reactions with allyl naphth-1-yl ether. Families of novel functionalized selenides, including bis[3-(3,4-dimethoxyphenyl)-2-methoxy- and -2-haloprop-1-yl] selenides, bis[3-(3,4-dimethoxyphenyl)-1-methoxy- and -1-haloprop-2-yl] selenides, bis[3-(naphth-1-yl)-1-methoxy- and -1-haloprop-1-yl] selenides, bis[3-(naphth-1-yl)-2-methoxy- and -2-haloprop-1-yl] selenides, were synthesized.
About the authors
M. V. Musalov
Favorskii Irkutsk Institute of Chemistry, SB, RAS
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
V. A. Yakimov
Favorskii Irkutsk Institute of Chemistry, SB, RAS
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
V. A. Potapov
Favorskii Irkutsk Institute of Chemistry, SB, RAS
Author for correspondence.
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
S. V. Amosova
Favorskii Irkutsk Institute of Chemistry, SB, RAS
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
S. V. Zinchenko
Favorskii Irkutsk Institute of Chemistry, SB, RAS
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
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