Lanthanide Double-Decker Complexes with Tetra-tert-butyltetrabenzoporphyrin and Phthalocyanine Ligands. Synthesis and Properties
- Authors: Koptyaev A.I.1, Galanin N.E.1, Shaposhnikov G.P.1
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Issue: Vol 55, No 7 (2019)
- Pages: 944-950
- Section: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/220839
- DOI: https://doi.org/10.1134/S1070428019070042
- ID: 220839
Cite item
Abstract
Mixed-ligand double-decker lutetium, erbium, dysprosium, gadolinium, and europium complexes with tetra-tert-butyltetrabenzoporphyrin and phthalocyanine have been synthesized, and their structure was confirmed by IR, 1H NMR, and mass spectra. Relations have been found between the electronic absorption and luminescence spectra of the complexes and radius of the central metal ion.
About the authors
A. I. Koptyaev
Ivanovo State University of Chemistry and Technology
Email: nik-galanin@yandex.ru
Russian Federation, Ivanovo
N. E. Galanin
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: nik-galanin@yandex.ru
Russian Federation, Ivanovo
G. P. Shaposhnikov
Ivanovo State University of Chemistry and Technology
Email: nik-galanin@yandex.ru
Russian Federation, Ivanovo
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