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Lanthanide Double-Decker Complexes with Tetra-tert-butyltetrabenzoporphyrin and Phthalocyanine Ligands. Synthesis and Properties


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Abstract

Mixed-ligand double-decker lutetium, erbium, dysprosium, gadolinium, and europium complexes with tetra-tert-butyltetrabenzoporphyrin and phthalocyanine have been synthesized, and their structure was confirmed by IR, 1H NMR, and mass spectra. Relations have been found between the electronic absorption and luminescence spectra of the complexes and radius of the central metal ion.

About the authors

A. I. Koptyaev

Ivanovo State University of Chemistry and Technology

Email: nik-galanin@yandex.ru
Russian Federation, Ivanovo

N. E. Galanin

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: nik-galanin@yandex.ru
Russian Federation, Ivanovo

G. P. Shaposhnikov

Ivanovo State University of Chemistry and Technology

Email: nik-galanin@yandex.ru
Russian Federation, Ivanovo

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