Catalytic Synthesis of Methylthiophenes


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Abstract

The gas-phase reaction of dimethyl disulfide with thiophene over Co/HZSM-5 catalyst in a helium medium under atmospheric pressure at 250–350°C gave a mixture of mono-, di-, tri-, and tetramethylthiophenes with an overall selectivity of 94–96%.

About the authors

A. V. Mashkina

Boreskov Institute of Catalysis, Siberian Branch

Author for correspondence.
Email: amash@catalysis.ru
Russian Federation, pr. Akad. Lavrent’eva 5, Novosibirsk, 630090

L. N. Khairulina

Boreskov Institute of Catalysis, Siberian Branch

Email: amash@catalysis.ru
Russian Federation, pr. Akad. Lavrent’eva 5, Novosibirsk, 630090

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