Synthesis of (3-Hydroxyadamantan-1-yl)methanols
- 作者: Ivleva E.A.1, Pogulyaiko A.V.1, Klimochkin Y.N.1
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隶属关系:
- Samara State Technical University
- 期: 卷 54, 编号 9 (2018)
- 页面: 1294-1300
- 栏目: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/218848
- DOI: https://doi.org/10.1134/S107042801809004X
- ID: 218848
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详细
A convenient procedure has been developed for the synthesis of (3-hydroxyadamantan-1-yl)-methanols on the basis of nitroxylation of adamantan-1-ylmethanols with fuming nitring acid and subsequent reduction of intermediate nitric acid esters with hydrazine hydrate. The title diols have also been obtained by the reduction of 1-nitroxy-3-(nitroxymethyl)adamantanes. The nitroxylation process is accompanied by oxidation with the formation of substituted adamantane-1-carboxylic acids.
作者简介
E. Ivleva
Samara State Technical University
编辑信件的主要联系方式.
Email: elena.a.ivleva@yandex.com
俄罗斯联邦, ul. Molodogvardeiskaya 244, Samara, 443100
A. Pogulyaiko
Samara State Technical University
Email: elena.a.ivleva@yandex.com
俄罗斯联邦, ul. Molodogvardeiskaya 244, Samara, 443100
Yu. Klimochkin
Samara State Technical University
Email: elena.a.ivleva@yandex.com
俄罗斯联邦, ul. Molodogvardeiskaya 244, Samara, 443100
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