Email this article Catalytic Reaction of Ethyl 2-Diazo-3-oxobutanoate with Alcohols
- Authors: Sakhabutdinova G.N.1, Baikova I.P.2, Raskil’dina G.Z.1, Zlotskii S.S.1, Sultanova R.M.1,2
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Affiliations:
- Ufa State Petroleum Technological University
- Ufa Institute of Chemistry
- Issue: Vol 54, No 3 (2018)
- Pages: 373-376
- Section: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/217248
- DOI: https://doi.org/10.1134/S1070428018030016
- ID: 217248
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Abstract
The effect of the structure of alcohols on their reaction with ethyl 2-diazo-3-oxobutanoate catalyzed by copper(II) trifluoromethanesulfonate has been studied. The corresponding ethyl 2-alkoxy-3-oxobutanoates were obtained in quantitative yield from primary alcohols. Introduction of a 1,3-dioxolane or 1,3-dioxane fragment into the alcohol molecule changes the reaction direction toward the formation of polyoxa macrocycles that are products of formal insertion of the diazo ester into the carbon–oxygen bond.
About the authors
G. N. Sakhabutdinova
Ufa State Petroleum Technological University
Email: graskildina444@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, Bashkortostan, 450062
I. P. Baikova
Ufa Institute of Chemistry
Email: graskildina444@mail.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
G. Z. Raskil’dina
Ufa State Petroleum Technological University
Author for correspondence.
Email: graskildina444@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, Bashkortostan, 450062
S. S. Zlotskii
Ufa State Petroleum Technological University
Email: graskildina444@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, Bashkortostan, 450062
R. M. Sultanova
Ufa State Petroleum Technological University; Ufa Institute of Chemistry
Email: graskildina444@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, Bashkortostan, 450062; pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
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