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Pincer Receptors for Anions Based on Triazolyl Bile Acids


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Abstract

Copper-catalyzed 1,3-dipolar cycloaddition of azides to acetylenes successfully afforded pincer bistriazolium receptor containing two lithocholic acid fragments and phenylphosphonic diamide bridge. The obtained receptor showed high complexing power toward fluoride ions and organic acid anions, which decreased in the series fluoride > succinate ≥ malonate > oxalate ≥ lithocholate > benzoate > acetate > hydrogen sulfate > bromide.

About the authors

N. V. Lukashev

Faculty of Chemistry

Author for correspondence.
Email: nvlukashev@gmail.com
Russian Federation, Leninskie gory 1, Moscow, 119991

D. A. Erzunov

Faculty of Chemistry

Email: nvlukashev@gmail.com
Russian Federation, Leninskie gory 1, Moscow, 119991

G. V. Latyshev

Faculty of Chemistry

Email: nvlukashev@gmail.com
Russian Federation, Leninskie gory 1, Moscow, 119991

A. D. Averin

Faculty of Chemistry

Email: nvlukashev@gmail.com
Russian Federation, Leninskie gory 1, Moscow, 119991

I. P. Beletskaya

Faculty of Chemistry

Email: nvlukashev@gmail.com
Russian Federation, Leninskie gory 1, Moscow, 119991

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