Synthesis of [3-(trimethylsilyl)prop-2-yn-1-yl] selenides

M. V. Musalov; M. V. Andreev; S. V. Amosova; L. I. Larina; V. A. Potapov

doi:10.1134/S1070428017100049

Synthesis of [3-(trimethylsilyl)prop-2-yn-1-yl] selenides

Authors: Musalov M.V.¹, Andreev M.V.¹, Amosova S.V.¹, Larina L.I.¹, Potapov V.A.¹
Affiliations:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Issue: Vol 53, No 10 (2017)
Pages: 1510-1513
Section: Article
URL: https://journals.rcsi.science/1070-4280/article/view/216790
DOI: https://doi.org/10.1134/S1070428017100049
ID: 216790

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Abstract

Efficient and selective methods have been developed for the synthesis of previously unknown organyl [3-(trimethylsilyl)prop-2-yn-1-yl] selenides, organyl prop-2-yn-1-yl selenides, and bis[3-(trimethylsilyl) prop-2-yn-1-yl] selenide by reactions of 3-bromo-1-(trimethylsilyl)prop-1-yne with the corresponding organylselenolates and sodium selenide generated from diorganyl diselenides or elemental selenium by the action of sodium tetrahydridoborate.