Synthesis of thiols from isobornylphenols
- Authors: Chukicheva I.Y.1, Sukrusheva O.V.1, Kutchin A.V.1
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Affiliations:
- Institute of Chemistry, Komi Scientific Center, Ural Branch
- Issue: Vol 53, No 4 (2017)
- Pages: 520-524
- Section: Review
- URL: https://journals.rcsi.science/1070-4280/article/view/216044
- DOI: https://doi.org/10.1134/S1070428017040042
- ID: 216044
Cite item
Abstract
4-(3-Sulfanylpropyl)-2-isobornyl-6-methylphenol and 4-(sulfanylmethyl)-2,6-diisobornylphenol were synthesized from the corresponding 4-(bromoalkyl)phenols according to known procedures. Isobornylphenol with a trimethylene linker was converted into thiol by alkaline hydrolysis of thiouronium salt. The methylene-bridged analog was obtained by reduction of S-benzyl thioacetate with LiAlH4.
About the authors
I. Yu. Chukicheva
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: sukrusheva@mail.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982
O. V. Sukrusheva
Institute of Chemistry, Komi Scientific Center, Ural Branch
Author for correspondence.
Email: sukrusheva@mail.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982
A. V. Kutchin
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: sukrusheva@mail.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982
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