Alkylation of 2-methylimidazole with iodomethylsilanes

N. O. Yarosh; L. V. Zhilitskaya; L. G. Shagun; I. A. Dorofeev; L. I. Larina

doi:10.1134/S1070428017030162

Alkylation of 2-methylimidazole with iodomethylsilanes

Authors: Yarosh N.O.¹, Zhilitskaya L.V.¹, Shagun L.G.¹, Dorofeev I.A.¹, Larina L.I.¹
Affiliations:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Issue: Vol 53, No 3 (2017)
Pages: 413-417
Section: Article
URL: https://journals.rcsi.science/1070-4280/article/view/215939
DOI: https://doi.org/10.1134/S1070428017030162
ID: 215939

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Abstract

2-Methyl-1,3-bis[(1-methylsilolan-1-yl)methyl]-1H-imidazolium triiodide, 1,3-bis{[dimethyl-(phenyl)silyl]methyl}-2-methyl-1H-imidazolium iodide and triiodide, and cyclic 3,3,5,5,10-pentamethyl-4-oxa-7-aza-1-azonia-3,5-disilabicyclo[5.2.1]deca-1(10),8-diene iodide were synthesized by solvent-free reactions of 2-methyl-1H-imidazole with 1-(iodomethyl)-1-methylsilolane, (iodomethyl)(dimethyl)phenylsilane, and ethynyl(iodomethyl)(dimethyl)silanes, respectively, in the absence of base catalyst.