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Reactions of γ-sultones containing a polycyclic fragment


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Abstract

Hydrolytic cleavage of cage γ-sultones have been studied. Alkaline hydrolysis of homoadamantane γ-sultone leads to the formation of sulfonates with erythro configuration. The reduction of homoadamantane γ-sultone with LiAlH4–AlCl3 yields desulfurization and deoxygenation products.

About the authors

M. V. Leonova

Samara State Technical University

Author for correspondence.
Email: mvleon@mail.ru
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100

M. R. Baimuratov

Samara State Technical University

Email: mvleon@mail.ru
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100

Yu. N. Klimochkin

Samara State Technical University

Email: mvleon@mail.ru
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100

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