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Catalytic synthesis and stereostructure of 1,2,3-trisubstituted decahydroisoquinolines


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Abstract

Liquid-phase catalytic reduction of 1,2,3-substituted 5,6,7,8-tetrahydroisoquinolinium perchlorates was investigated. The reaction proceeds stereodirectionally affording cis-decahydroisoquinolines. The probable scheme of reaction products formation is suggested. The structure of compounds obtained was established by IR and 13C NMR spectroscopy.

About the authors

P. V. Reshetov

Razumovskii Saratov Medical University

Author for correspondence.
Email: reshetoff_pv@mail.ru
Russian Federation, ul. B. Kazachya 112, Saratov, 410012

R. V. Seller

Razumovskii Saratov Medical University

Email: reshetoff_pv@mail.ru
Russian Federation, ul. B. Kazachya 112, Saratov, 410012

A. G. Golikov

Razumovskii Saratov Medical University

Email: reshetoff_pv@mail.ru
Russian Federation, ul. B. Kazachya 112, Saratov, 410012

M. I. Skuratova

Razumovskii Saratov Medical University

Email: reshetoff_pv@mail.ru
Russian Federation, ul. B. Kazachya 112, Saratov, 410012

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