Synthesis and some transformations of 3-(2,2-dimethyloxan-4-yl)-4-methylpentanenitrile
- 作者: Harutyunyan N.S.1,2, Nazaryan R.L.1,2, Hakobyan L.A.1,2, Panosyan H.A.3,2, Gevorgyan G.A.1,2
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隶属关系:
- Mndzhoyan Institute of Fine Organic Chemistry
- Scientific Technological Center of Organic and Pharmaceutical Chemistry
- Molecular Structure Research Center
- 期: 卷 53, 编号 1 (2017)
- 页面: 57-61
- 栏目: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/215616
- DOI: https://doi.org/10.1134/S1070428017010109
- ID: 215616
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详细
2,2-Dimethyloxane-4-carbaldehyde reacted with ethyl cyanoacetate to give ethyl 2-cyano-3-(2,2-dimethyloxan-4-yl)prop-2-enoate whose reaction with isopropylmagnesium bromide afforded ethyl 2-cyano-3-(2,2-dimethyloxan-4-yl)-4-methylpentanoate. Elimination of the ester group from the latter led to the formation of 3-(2,2-dimethyloxan-4-yl)-4-methylpentanenitrile.
作者简介
N. Harutyunyan
Mndzhoyan Institute of Fine Organic Chemistry; Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: gyulgev@gmail.com
亚美尼亚, Yerevan; pr. Azatutyan 26, Yerevan, 0014
R. Nazaryan
Mndzhoyan Institute of Fine Organic Chemistry; Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: gyulgev@gmail.com
亚美尼亚, Yerevan; pr. Azatutyan 26, Yerevan, 0014
L. Hakobyan
Mndzhoyan Institute of Fine Organic Chemistry; Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: gyulgev@gmail.com
亚美尼亚, Yerevan; pr. Azatutyan 26, Yerevan, 0014
H. Panosyan
Molecular Structure Research Center; Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: gyulgev@gmail.com
亚美尼亚, Yerevan; pr. Azatutyan 26, Yerevan, 0014
G. Gevorgyan
Mndzhoyan Institute of Fine Organic Chemistry; Scientific Technological Center of Organic and Pharmaceutical Chemistry
编辑信件的主要联系方式.
Email: gyulgev@gmail.com
亚美尼亚, Yerevan; pr. Azatutyan 26, Yerevan, 0014
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