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Selective hydrogenation of conjugated unsaturated ketones containing a hydroxyaryl substituent in the β-position


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Abstract

A high selectivity was achieved in the Ni2B-catalyzed hydrogenation of α,β-unsaturated ketones containing a hydroxyaryl (phenolic) substituent in the β-position. The developed hydrogenation procedure was used to synthesize natural compounds of the phenylpropane series and their structural analogs.

About the authors

V. N. Kovalenko

Belarusian State University; Belarusian State Pedagogical University

Author for correspondence.
Email: kovalenkovn@rambler.ru
Belarus, pr. Nezavisimosti 4, Minsk, 220030; ul. Sovetskaya 18, Minsk, 220030

A. S. Pratsko

Belarusian State Pedagogical University

Email: kovalenkovn@rambler.ru
Belarus, ul. Sovetskaya 18, Minsk, 220030

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