Synthesis of (–)-(3a R ,4 R ,5 S ,6a S )-4-[(acetoxy)methyl]-1-oxohexahydro-1 H -cyclopenta[ c ]furan-5-yl Acetate

A. M. Gimazetdinov; V. V. Loza; A. Z. Al’mukhametov; M. S. Miftakhov

doi:10.1134/S1070428016040072

Synthesis of (–)-(3aR,4R,5S,6aS)-4-[(acetoxy)methyl]-1-oxohexahydro-1H-cyclopenta[c]furan-5-yl Acetate

作者: Gimazetdinov A.M.¹, Loza V.V.¹, Al’mukhametov A.Z.¹, Miftakhov M.S.¹
隶属关系:
1. Institute of Chemistry
期: 卷 52, 编号 4 (2016)
页面: 523-525
栏目: Review
URL: https://journals.rcsi.science/1070-4280/article/view/214069
DOI: https://doi.org/10.1134/S1070428016040072
ID: 214069

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详细

A new 1,2,3,4-functionalized cyclopentane, (–)-(3aR,4R,5S,6aS)-4-[(acetoxy)methyl]-1-oxohexahydro-1H-cyclopenta[c]furan-5-yl acetate, has been synthesized by cleavage of a tricyclic bowl-shaped aminal, (2aR,3S,4aS,6bR)-3-hydroxy-6-[(1R)-1-phenylethyl]-octahydro-5H-1-oxa-6-azacyclopenta[cd]pentalen-5-one.