Conformational Transitions of Silk Fibroin in Solutions under the Action of Ultrasound


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Abstract

The influence of ultrasonic treatment on the fibroin conformation in solutions and films was studied by dynamic light scattering, FTIR spectroscopy, and X-ray diffraction. Ultrasonic treatment of fibroin solutions leads to a decrease in the fraction of the α-helical conformation and to an increase in the fraction of β-turns and β-structure in the fibroin structure in the films regenerated from solutions.

About the authors

A. I. Susanin

St. Petersburg State University of Industrial Technologies and Design

Author for correspondence.
Email: drsusanin@yandex.ru
Russian Federation, St. Petersburg, 190068

E. S. Sashina

St. Petersburg State University of Industrial Technologies and Design

Email: drsusanin@yandex.ru
Russian Federation, St. Petersburg, 190068

V. V. Zakharov

Petersburg Nuclear Physics Institute named by B.P.Konstantinov of National Research Centre ”Kurchatov Institute,”; Institute of Macromolecular Compounds; Peter the Great St. Petersburg Polytechnic University

Email: drsusanin@yandex.ru
Russian Federation, Gatchina, Leningrad oblast, 188300; St. Petersburg, 199034; St. Petersburg, 195251

M. Zaborski

Lodz Technical University

Email: drsusanin@yandex.ru
Poland, Lodz

D. A. Kashirskii

St. Petersburg State University of Industrial Technologies and Design

Email: drsusanin@yandex.ru
Russian Federation, St. Petersburg, 190068

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