Heat-Resistant Network Block Copolymers Based on Rolivsans Modified with Tetracarboxylic Anhydrides and Aromatic Tetraamines


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The efficiency of a new approach to structural-chemical modification of unsaturated thermosetting resins was demonstrated by the example of curing of rolivsans containing small additions (0.5–2.0 wt %) of aromatic tetracarboxylic dianhydrides and aromatic tetraamines. As shown by dynamic mechanical and thermal analysis, the heat resistance of the modified matrix of the cured rolivsan, which is mainly used as a heat-resistant polymer compound for electric insulation, increases from 280 to 340–375°С, and the rigidity parameters decrease by a factor of 3–6, which is of much practical interest.

作者简介

B. Zaitsev

Institute of Macromolecular Compounds

编辑信件的主要联系方式.
Email: zaitsev@hq.macro.ru
俄罗斯联邦, St. Petersburg, 199034

I. Shvabskaya

Institute of Macromolecular Compounds

Email: zaitsev@hq.macro.ru
俄罗斯联邦, St. Petersburg, 199034

L. Kleptsova

Institute of Macromolecular Compounds

Email: zaitsev@hq.macro.ru
俄罗斯联邦, St. Petersburg, 199034

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