Email this article Production of Ethylene, CO, and Hydrogen by Oxidative Cracking of Oil Refinery Gas Components
- Authors: Ozerskii A.V.1,2, Nikitin A.V.1,2, Sedov I.V.1,3, Fokin I.G.1, Savchenko V.I.1, Arutyunov V.S.1,2,3
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Affiliations:
- Institute of Problems of Chemical Physics
- Semenov Institute of Chemical Physics
- Moscow State University
- Issue: Vol 91, No 12 (2018)
- Pages: 2065-2075
- Section: Specific Technological Processes
- URL: https://journals.rcsi.science/1070-4272/article/view/216175
- DOI: https://doi.org/10.1134/S1070427218120200
- ID: 216175
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Abstract
Flowsheets based on the results of experimental studies and detailed kinetic modeling were suggested for oxidative cracking of oil refinery gas components to obtain ethylene, CO, and hydrogen. The calculations show that oxidative cracking alone does not allow production of ethylene and СО in ratios required for the further catalytic carbonylation and hydroformylation of ethylene. Matrix conversion of a part of oxy-cracking products is suggested as an additional step for producing CO and hydrogen.
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About the authors
A. V. Ozerskii
Institute of Problems of Chemical Physics; Semenov Institute of Chemical Physics
Author for correspondence.
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 117977
A. V. Nikitin
Institute of Problems of Chemical Physics; Semenov Institute of Chemical Physics
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 117977
I. V. Sedov
Institute of Problems of Chemical Physics; Moscow State University
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119991
I. G. Fokin
Institute of Problems of Chemical Physics
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. I. Savchenko
Institute of Problems of Chemical Physics
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. S. Arutyunov
Institute of Problems of Chemical Physics; Semenov Institute of Chemical Physics; Moscow State University
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 117977; Moscow, 119991
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