Electrochemical conversion of aqueous ethanol solution in an electrolyzer with a solid polymer electrolyte
- Авторы: Pushkareva I.V.1,2, Pushkarev A.S.1,2, Grigoriev S.A.1, Lyutikova E.K.2, Akel’kina S.V.2, Osina M.A.1, Slavcheva E.P.3, Fateev V.N.2
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Учреждения:
- National Research University “Moscow Power Engineering Institute,”
- National Research Centre “Kurchatov Institute,”
- Acad. Evgeni Budevski Institute of Electrochemistry and Energy Systems
- Выпуск: Том 89, № 12 (2016)
- Страницы: 2109-2111
- Раздел: Brief Communications
- URL: https://journals.rcsi.science/1070-4272/article/view/214623
- DOI: https://doi.org/10.1134/S1070427216120260
- ID: 214623
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Аннотация
The electrochemical conversion of an aqueous ethanol solution (40 vol %) in an electrolysis cell with a solid polymer electrolyte in the presence of various electrocatalysts (Pt, Ir, Ir0.3Ru0.3Sn0.4O2, and Pt0.5Ru0.5) was studied. The electrocatalytic conversion of the ethanol solution at low current densities (up to 0.3 A cm−2) is characterized by a significant (by up to 50%) decrease in the cell voltage relative to water electrolysis. Possible diffusion of ethanol from the anode zone to the cathode zone will not significantly affect operation of the platinum electrocatalyst.
Об авторах
I. Pushkareva
National Research University “Moscow Power Engineering Institute,”; National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Россия, ul. Krasnokazarmennaya 14, Moscow, 111250; pl. Kurchatova 1, Moscow, 123182
A. Pushkarev
National Research University “Moscow Power Engineering Institute,”; National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Россия, ul. Krasnokazarmennaya 14, Moscow, 111250; pl. Kurchatova 1, Moscow, 123182
S. Grigoriev
National Research University “Moscow Power Engineering Institute,”
Автор, ответственный за переписку.
Email: sergey.grigoriev@outlook.com
Россия, ul. Krasnokazarmennaya 14, Moscow, 111250
E. Lyutikova
National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Россия, pl. Kurchatova 1, Moscow, 123182
S. Akel’kina
National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Россия, pl. Kurchatova 1, Moscow, 123182
M. Osina
National Research University “Moscow Power Engineering Institute,”
Email: sergey.grigoriev@outlook.com
Россия, ul. Krasnokazarmennaya 14, Moscow, 111250
E. Slavcheva
Acad. Evgeni Budevski Institute of Electrochemistry and Energy Systems
Email: sergey.grigoriev@outlook.com
Болгария, Acad. Georgi Bonchev str. 10, Sofia, 1113
V. Fateev
National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Россия, pl. Kurchatova 1, Moscow, 123182
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