Enviar artigo por via de e-mail Ethenolysis of C5+ Alkenes as a Method for Synthesis of Propylene
- Autores: Buluchevskii E.A.1,2, Saifullina L.F.1, Lavrenov A.V.1, Karpova T.R.1, Glazov N.A.2
-
Afiliações:
- Institute of Hydrocarbons Processing, Siberian Branch
- Omsk F.M. Dostoevsky State University
- Edição: Volume 90, Nº 12 (2017)
- Páginas: 1893-1899
- Seção: Catalysis
- URL: https://journals.rcsi.science/1070-4272/article/view/215441
- DOI: https://doi.org/10.1134/S1070427217120011
- ID: 215441
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
Thermodynamic calculations demonstrated that, when any C5+ alkene is subjected to ethenolysis in an excess of ethylene on a catalyst providing the occurrence of a metathesis and positional isomerization, the main reaction product is propylene. The results of the calculations were confirmed experimentally for the cases of ethenolysis of hexene-1 and heptene-1 on Re2O7/SO42-/ZrO2–Al2O3 and Re2O7/B2O3–Al2O3 catalysts.
Sobre autores
E. Buluchevskii
Institute of Hydrocarbons Processing, Siberian Branch; Omsk F.M. Dostoevsky State University
Autor responsável pela correspondência
Email: bulu@ihcp.ru
Rússia, ul. Neftezavodskaya 54, Omsk, 644040; ul. Neftezavodskaya 11, Omsk, 644053
L. Saifullina
Institute of Hydrocarbons Processing, Siberian Branch
Email: bulu@ihcp.ru
Rússia, ul. Neftezavodskaya 54, Omsk, 644040
A. Lavrenov
Institute of Hydrocarbons Processing, Siberian Branch
Email: bulu@ihcp.ru
Rússia, ul. Neftezavodskaya 54, Omsk, 644040
T. Karpova
Institute of Hydrocarbons Processing, Siberian Branch
Email: bulu@ihcp.ru
Rússia, ul. Neftezavodskaya 54, Omsk, 644040
N. Glazov
Omsk F.M. Dostoevsky State University
Email: bulu@ihcp.ru
Rússia, ul. Neftezavodskaya 11, Omsk, 644053
Arquivos suplementares
