Optical and conductive properties of functional materials extracted from coal tar pitches treated by air oxidization method
- Authors: Zhang J.1, Yu J.L.1, Zhang X.H.1, Xu G.Y.1, An B.G.1, Ju D.Y.2, Wang J.1, Wu X.Y.1, Zhou W.M.1
-
Affiliations:
- Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
- School of Materials and Metallurgy
- Issue: Vol 90, No 4 (2017)
- Pages: 625-632
- Section: Various Technological Processes
- URL: https://journals.rcsi.science/1070-4272/article/view/214859
- DOI: https://doi.org/10.1134/S107042721704019X
- ID: 214859
Cite item
Abstract
The oligomers having the blue photoluminescence and conductivities of 5 × 10–7–7.4 × 10–4 S m–1 after doping by iodine are extracted successfully from coal tar pitches which were dealt with by the air oxidization method at 350°C. Meanwhile, it is observed that extracted materials have the blue photoluminescence with the fluorescence quantum yield of 7–10.2%. In these cases, we used the solutions of toluene and pyridine to extract these functional materials from coal tar pitches. Consequently, we consider these extracted materials showing the advantages in the application of fabricating the electronic devices, because it can decrease the production cost remarkably than use of the materials obtained by general organic synthesis methods. Finally, this research also can provide the one of beneficial references for solving the serious problem of overproduction of coal tar pitches in China. The oligomers having the blue photoluminescence and conductivities of 5 × 10–7–7.4 × 10–4 S m–1 after doping by iodine are extracted successfully from coal tar pitches which were dealt with by the air oxidization method at 350°C. Meanwhile, it is observed that extracted materials have the blue photoluminescence with the fluorescence quantum yield of 7–10.2%. In these cases, we used the solutions of toluene and pyridine to extract these functional materials from coal tar pitches. Consequently, we consider these extracted materials showing the advantages in the application of fabricating the electronic devices, because it can decrease the production cost remarkably than use of the materials obtained by general organic synthesis methods. Finally, this research also can provide the one of beneficial references for solving the serious problem of overproduction of coal tar pitches in China.
About the authors
Jian Zhang
Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
Email: aszhou15242870697@163.com
China, Anshan, 114051
Jiang Long Yu
Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
Email: aszhou15242870697@163.com
China, Anshan, 114051
Xue Hu Zhang
Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
Email: aszhou15242870697@163.com
China, Anshan, 114051
Gui Ying Xu
Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
Email: aszhou15242870697@163.com
China, Anshan, 114051
Bai Gang An
Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
Email: aszhou15242870697@163.com
China, Anshan, 114051
Dong Ying Ju
School of Materials and Metallurgy
Email: aszhou15242870697@163.com
China, Anshan, 114051
Jing Wang
Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
Email: aszhou15242870697@163.com
China, Anshan, 114051
Xin Ying Wu
Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
Email: aszhou15242870697@163.com
China, Anshan, 114051
Wei Min Zhou
Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering
Author for correspondence.
Email: aszhou15242870697@163.com
China, Anshan, 114051
Supplementary files
