Specific process features of epoxidation of fatty acid methyl esters of vegetable oils with performic acid generated in situ
- Autores: Sapunov V.N.1, Voronov M.S.1, Gustyakova S.I.1, Kozeeva I.S.1, Makarova E.M.1
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Afiliações:
- Mendeleev University of Chemical Technology of Russia
- Edição: Volume 90, Nº 1 (2017)
- Páginas: 53-62
- Seção: Organic Synthesis and Industrial Organic Chemistry
- URL: https://journals.rcsi.science/1070-4272/article/view/214644
- DOI: https://doi.org/10.1134/S1070427217010098
- ID: 214644
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Resumo
Physicochemical relationships of the phase distribution of the reactants in epoxidation of fatty acid methyl esters of vegetable oils with performic acid generated in situ were determined.. The progress of epoxidation is accompanied by redistribution of the organic and aqueous phase volumes. The major cause of changes in the phase volumes is the transfer of peroxide oxygen from the aqueous phase into the organic phase upon formation of epoxy groups. A comparable change in the phase volumes is due to reactive extraction of aqueous phase components with the epoxy compounds formed.
Sobre autores
V. Sapunov
Mendeleev University of Chemical Technology of Russia
Autor responsável pela correspondência
Email: sapunovvals@gmail.com
Rússia, Miusskaya pl. 9, Moscow, 125047
M. Voronov
Mendeleev University of Chemical Technology of Russia
Email: sapunovvals@gmail.com
Rússia, Miusskaya pl. 9, Moscow, 125047
S. Gustyakova
Mendeleev University of Chemical Technology of Russia
Email: sapunovvals@gmail.com
Rússia, Miusskaya pl. 9, Moscow, 125047
I. Kozeeva
Mendeleev University of Chemical Technology of Russia
Email: sapunovvals@gmail.com
Rússia, Miusskaya pl. 9, Moscow, 125047
E. Makarova
Mendeleev University of Chemical Technology of Russia
Email: sapunovvals@gmail.com
Rússia, Miusskaya pl. 9, Moscow, 125047
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