Palladium-catalyzed synthesis of diarylbenzenes from coupling reactions between equal amount of diiodoarenes and arylboronic acids


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We reported a highly effective Pd-catalytic system for the synthesis of diarylbenzenes through Suzuki-type reaction between equal amount of diiodoarenes and arylboronic acids. This preferential oxidative addition resulted in such high selectivity.

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Jincheng Mao

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science

Autor responsável pela correspondência
Email: jcmao@swpu.edu.cn
República Popular da China, Chengdu, 610500; Suzhou, 215123

Ran Li

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Email: jcmao@swpu.edu.cn
República Popular da China, Chengdu, 610500

Yue He

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science

Email: jcmao@swpu.edu.cn
República Popular da China, Suzhou, 215123

Xiaojiang Yang

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Email: jcmao@swpu.edu.cn
República Popular da China, Chengdu, 610500

Dingli Wang

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Email: jcmao@swpu.edu.cn
República Popular da China, Chengdu, 610500

Yang Zhang

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Email: jcmao@swpu.edu.cn
República Popular da China, Chengdu, 610500

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