Palladium-catalyzed synthesis of diarylbenzenes from coupling reactions between equal amount of diiodoarenes and arylboronic acids


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Abstract

We reported a highly effective Pd-catalytic system for the synthesis of diarylbenzenes through Suzuki-type reaction between equal amount of diiodoarenes and arylboronic acids. This preferential oxidative addition resulted in such high selectivity.

About the authors

Jincheng Mao

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science

Author for correspondence.
Email: jcmao@swpu.edu.cn
China, Chengdu, 610500; Suzhou, 215123

Ran Li

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Email: jcmao@swpu.edu.cn
China, Chengdu, 610500

Yue He

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science

Email: jcmao@swpu.edu.cn
China, Suzhou, 215123

Xiaojiang Yang

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Email: jcmao@swpu.edu.cn
China, Chengdu, 610500

Dingli Wang

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Email: jcmao@swpu.edu.cn
China, Chengdu, 610500

Yang Zhang

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Email: jcmao@swpu.edu.cn
China, Chengdu, 610500

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