Comparison of catalytic properties of systems based on nickel complexes with 1,4-diaza-1,3-butadiene ligands in reactions of styrene hydrogenation and ethylene polymerization

Resumo

Turnover frequencies of catalytic systems based on nickel complexes with 1,4-diaza-1,3-butadiene (α-diimine) ligands in the reactions of styrene hydrogenation and ethylene polymerization were determined. Results are presented of a study by the electron paramagnetic resonance method and IR spectroscopy of 1,4-diaza-1,3-butadiene complexes of nickel(II) and anion radicals formed in the interaction of the starting components under the conditions of catalysis. It was shown that the paramagnetic Ni(I) complexes are precursors of complexes catalytically active in the hydrogenation and polymerization reactions.