Optical and conductive properties of functional materials extracted from coal tar pitches treated by air oxidization method


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Abstract

The oligomers having the blue photoluminescence and conductivities of 5 × 10–7–7.4 × 10–4 S m–1 after doping by iodine are extracted successfully from coal tar pitches which were dealt with by the air oxidization method at 350°C. Meanwhile, it is observed that extracted materials have the blue photoluminescence with the fluorescence quantum yield of 7–10.2%. In these cases, we used the solutions of toluene and pyridine to extract these functional materials from coal tar pitches. Consequently, we consider these extracted materials showing the advantages in the application of fabricating the electronic devices, because it can decrease the production cost remarkably than use of the materials obtained by general organic synthesis methods. Finally, this research also can provide the one of beneficial references for solving the serious problem of overproduction of coal tar pitches in China. The oligomers having the blue photoluminescence and conductivities of 5 × 10–7–7.4 × 10–4 S m–1 after doping by iodine are extracted successfully from coal tar pitches which were dealt with by the air oxidization method at 350°C. Meanwhile, it is observed that extracted materials have the blue photoluminescence with the fluorescence quantum yield of 7–10.2%. In these cases, we used the solutions of toluene and pyridine to extract these functional materials from coal tar pitches. Consequently, we consider these extracted materials showing the advantages in the application of fabricating the electronic devices, because it can decrease the production cost remarkably than use of the materials obtained by general organic synthesis methods. Finally, this research also can provide the one of beneficial references for solving the serious problem of overproduction of coal tar pitches in China.

About the authors

Jian Zhang

Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering

Email: aszhou15242870697@163.com
China, Anshan, 114051

Jiang Long Yu

Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering

Email: aszhou15242870697@163.com
China, Anshan, 114051

Xue Hu Zhang

Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering

Email: aszhou15242870697@163.com
China, Anshan, 114051

Gui Ying Xu

Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering

Email: aszhou15242870697@163.com
China, Anshan, 114051

Bai Gang An

Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering

Email: aszhou15242870697@163.com
China, Anshan, 114051

Dong Ying Ju

School of Materials and Metallurgy

Email: aszhou15242870697@163.com
China, Anshan, 114051

Jing Wang

Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering

Email: aszhou15242870697@163.com
China, Anshan, 114051

Xin Ying Wu

Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering

Email: aszhou15242870697@163.com
China, Anshan, 114051

Wei Min Zhou

Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering

Author for correspondence.
Email: aszhou15242870697@163.com
China, Anshan, 114051

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