Hydro-Oxygenation of Furfural in the Presence of Ruthenium Catalysts Based on Al-HMS Mesoporous Support


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Ruthenium-containing catalyst based on an Al-HMS mesoporous aluminosilicate was synthesized, The mesoporous support and the catalyst on its basis were characterized by the methods of low-temperature desorption/adsorption of nitrogen, temperature-programmed desorption of ammonia, transmission electron microscopy, X-ray photoelectron microscopy, and energy-dispersive X-ray fluorescence analysis. The catalyst obtained was examined in the reaction of hydrodeoxygenation of the model compound of bio-oil, furfural, in the presence of water. The reaction was performed at initial hydrogen pressures of 1–7 MPa in the temperature range 200–300°C. It was shown that the catalyst under study exhibits a high activity in the hydrotransformation of furfural: the conversion was 100% in 1 h at a hydrogen pressure of 5 MPa and temperature of 200°C.

作者简介

E. Roldugina

Moscow Lomonosov State University

编辑信件的主要联系方式.
Email: rolduginakate@mail.ru
俄罗斯联邦, Moscow, 119991

N. Shayakhmetov

Moscow Lomonosov State University

Email: rolduginakate@mail.ru
俄罗斯联邦, Moscow, 119991

A. Maksimov

Moscow Lomonosov State University; Topchiev Institute of Petrochemical Synthesis

Email: rolduginakate@mail.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

E. Karakhanov

Moscow Lomonosov State University

Email: rolduginakate@mail.ru
俄罗斯联邦, Moscow, 119991

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