A Deep Analytical Study in the Oxidation Polymerization Desulfurization Process Using a Keggin-Type Polyoxometalate Catalyst: Characterization of Solid and Liquid Products
- Authors: Mansourian S.H.1, Shahhosseini S.1, Maleki A.2
-
Affiliations:
- School of Chemical Engineering
- Catalysts and Organic Synthesis Research Laboratory
- Issue: Vol 92, No 9 (2019)
- Pages: 1291-1305
- Section: Organic Synthesis and Industrial Organic Chemistry
- URL: https://journals.rcsi.science/1070-4272/article/view/216938
- DOI: https://doi.org/10.1134/S1070427219090155
- ID: 216938
Cite item
Abstract
In this study, oxidation of a model fuel, benzothiophene (BT) in n-decane, using polyoxometalate catalyst with Keggin structure has been investigated. The solid product evaluation was performed using gel permeation chromatography (GPC), thermal gravimetric analysis (TGA)/(DSC) differential scanning calorimeter, FTIR, proton and carbon nuclear magnetic resonance (1H + 13C NMR) spectrums, elementary (C, H, N and S) analyses. The results showed that the solid product was a polymer with a weighted average molecular weight (Mw) of 183030. In addition, the polymer was found to be sticky, branched and cross-linked. Moreover, for the first time, the role of the different solvents in the formation of the polymer was studied. It was revealed that the solvent intermolecular force plays an important role in polymerization so that the solvent with stronger molecular force did not participant in the polymerization. Ultimately gas chromatography-flame ionization detector (GC-FID) analysis showed the amount of desulfurization was about 81%.
About the authors
Seyed Hossein Mansourian
School of Chemical Engineering
Email: Shahrokh@iust.ac.ir
Iran, Islamic Republic of, Narmak, Tehran, 16846
Shahrokh Shahhosseini
School of Chemical Engineering
Author for correspondence.
Email: Shahrokh@iust.ac.ir
Iran, Islamic Republic of, Narmak, Tehran, 16846
Ali Maleki
Catalysts and Organic Synthesis Research Laboratory
Email: Shahrokh@iust.ac.ir
Iran, Islamic Republic of, Tehran, 16846-13114
Supplementary files
