Kinetics of Butadiene Polymerization in the Presence of the TiCl4-Al(i-C4H9)3 Catalytic System Physically Modified in Turbulent Flows: Results of Computational Experiments
- 作者: Tereshchenko K.A.1, Ulitin N.V.1, Shiyan D.A.1, Ziganshina A.S.1, Zakharov V.P.2
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隶属关系:
- Kazan National Research Technological University
- Bashkir State University
- 期: 卷 92, 编号 9 (2019)
- 页面: 1200-1209
- 栏目: Macromolecular Compounds and Polymeric Materials
- URL: https://journals.rcsi.science/1070-4272/article/view/216902
- DOI: https://doi.org/10.1134/S1070427219090039
- ID: 216902
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详细
The influence of the velocity of feeding the reaction mixture to a tubular turbulent diffuser-confuser apparatus and of the geometric parameters of the apparatus on the fields the flow turbulence kinetic energy and its dissipation rate was revealed in computational experiments with a model reaction, polymerization of butadiene in toluene in the presence of the TiCl4-Al(i-C4H9)3 catalytic system physically modified in turbulent flows. Correlation between the fields of the flow turbulence kinetic energy and its dissipation rate, on the one hand, and butadiene polymerization rate, on the other hand, is considered.
作者简介
K. Tereshchenko
Kazan National Research Technological University
Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
N. Ulitin
Kazan National Research Technological University
编辑信件的主要联系方式.
Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
D. Shiyan
Kazan National Research Technological University
Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
A. Ziganshina
Kazan National Research Technological University
Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
V. Zakharov
Bashkir State University
Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Zaki Validi 32, Ufa, Bashkortostan, 450076
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