Kinetics of Butadiene Polymerization in the Presence of the TiCl4-Al(i-C4H9)3 Catalytic System Physically Modified in Turbulent Flows: Results of Computational Experiments


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The influence of the velocity of feeding the reaction mixture to a tubular turbulent diffuser-confuser apparatus and of the geometric parameters of the apparatus on the fields the flow turbulence kinetic energy and its dissipation rate was revealed in computational experiments with a model reaction, polymerization of butadiene in toluene in the presence of the TiCl4-Al(i-C4H9)3 catalytic system physically modified in turbulent flows. Correlation between the fields of the flow turbulence kinetic energy and its dissipation rate, on the one hand, and butadiene polymerization rate, on the other hand, is considered.

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K. Tereshchenko

Kazan National Research Technological University

Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan, Tatarstan, 420015

N. Ulitin

Kazan National Research Technological University

编辑信件的主要联系方式.
Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan, Tatarstan, 420015

D. Shiyan

Kazan National Research Technological University

Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan, Tatarstan, 420015

A. Ziganshina

Kazan National Research Technological University

Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan, Tatarstan, 420015

V. Zakharov

Bashkir State University

Email: n.v.ulitin@mail.ru
俄罗斯联邦, ul. Zaki Validi 32, Ufa, Bashkortostan, 450076

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