Inhibiting Effect of Quinoline on the Hydroconversion of Dibenzothiophene and Naphthalene on Trimetallic NiCoMoS Catalysts Supported on Al2O3, SiO2, and SBA-15

Abstract

Trimetallic NiCoMo catalysts supported on γ-alumina (γ-Al₂O₃), amorphous silicon dioxide (SiO₂), and mesostructured silicate (SBA-15) with equal surface concentration of active components were synthesized, and their physicochemical characteristics, including the morphology of the active phase particles, were studied. The performance of the synthesized catalysts in target hydrotreating reactions at different concentrations of an organic nitrogen-containing inhibitor, quinoline (0–1000 ppmw nitrogen), was determined. The inhibiting effect of quinoline on the hydrodesulfurization and hydrogenation reactions occurring on the synthesized catalysts and the influence of the kind and properties of the support on this effect were evaluated.