Email this article Oxidative Cracking of Oil Refinery Gases
- Authors: Ozerskii A.V.1,2, Zimin Y.S.1,2, Komarov I.K.1,2,3, Nikitin A.V.1,2, Sedov I.V.1,3, Fokin I.G.1, Savchenko V.I.1, Arutyunov V.S.1,2,3
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Affiliations:
- Institute of Problems of Chemical Physics
- Semenov Federal Research Center of Chemical Physics
- Moscow State University
- Issue: Vol 92, No 12 (2019)
- Pages: 1745-1750
- Section: Various Technological Processes
- URL: https://journals.rcsi.science/1070-4272/article/view/216857
- DOI: https://doi.org/10.1134/S1070427219120162
- ID: 216857
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Abstract
Trials of oxidative cracking of ethane—propane—n-butane mixtures were performed on an installation with the productive capacity with respect to the gaseous feed of 5 m3 h−1. Ethylene, CO, and hydrogen are the major products of oxidative cracking of oil refinery gases; their total yield can exceed 90%. The yield of ethylene and CO is determined by the total concentration of alkanes in the mixture and is independent on the length of their hydrocarbon chain, whereas the hydrogen yield appreciably decreases with an increase in the alkane chain length. The trials demonstrated high efficiency of the production of ethylene, CO, and hydrogen by oxidative cracking of oil refinery gas mixture components.
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About the authors
A. V. Ozerskii
Institute of Problems of Chemical Physics; Semenov Federal Research Center of Chemical Physics
Author for correspondence.
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119334
Ya. S. Zimin
Institute of Problems of Chemical Physics; Semenov Federal Research Center of Chemical Physics
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119334
I. K. Komarov
Institute of Problems of Chemical Physics; Semenov Federal Research Center of Chemical Physics; Moscow State University
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119334; Moscow, 119991
A. V. Nikitin
Institute of Problems of Chemical Physics; Semenov Federal Research Center of Chemical Physics
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119334
I. V. Sedov
Institute of Problems of Chemical Physics; Moscow State University
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119991
I. G. Fokin
Institute of Problems of Chemical Physics
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. I. Savchenko
Institute of Problems of Chemical Physics
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. S. Arutyunov
Institute of Problems of Chemical Physics; Semenov Federal Research Center of Chemical Physics; Moscow State University
Email: alex.ozersky.1992@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119334; Moscow, 119991
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