Study of Structural Changes in LiNi0.8Co0.1Mn0.1O2 Cathode Material for Lithium-Ion Batteries by X-Ray Diffraction Analysis in the In Situ Mode
- Authors: Novikov P.A.1,2, Kim A.E.1,2, Pushnitsa K.A.1,3, Quingsheng W.1,2, Maksimov M.Y.2, Popovich A.A.2
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Affiliations:
- Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute
- Peter the Great St. Petersburg Polytechnic University
- St. Petersburg State Technological Institute (Technical University)
- Issue: Vol 92, No 7 (2019)
- Pages: 1013-1019
- Section: Applied Electrochemistry and Metal Corrosion Protection
- URL: https://journals.rcsi.science/1070-4272/article/view/216637
- DOI: https://doi.org/10.1134/S1070427219070188
- ID: 216637
Cite item
Abstract
Structural changes in a promising cathode material LiNi0.8Co0.1Mn0.1O2 for lithium-ion batteries were in situ studied by X-ray diffraction analysis in the course of electrochemical reactions. The Rietveld method and TOPAS 5 software package were used to examine changes in the unit cell parameters of LiNi0.8Co0.1Mn0.1O2 and the reasons for these changes. It was found that the unit cell volume increases by 2% relative to the discharged state (2.7 V) upon charging to 4.2 V.
About the authors
P. A. Novikov
Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute; Peter the Great St. Petersburg Polytechnic University
Email: pushnitsa.k@gmail.com
China, Zhejiang, Changxing County; St. Petersburg, 195251
A. E. Kim
Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute; Peter the Great St. Petersburg Polytechnic University
Author for correspondence.
Email: artem_7.kim@mail.ru
China, Zhejiang, Changxing County; St. Petersburg, 195251
K. A. Pushnitsa
Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute; St. Petersburg State Technological Institute (Technical University)
Author for correspondence.
Email: pushnitsa.k@gmail.com
China, Zhejiang, Changxing County; St. Petersburg, 190013
Wang Quingsheng
Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute; Peter the Great St. Petersburg Polytechnic University
Email: pushnitsa.k@gmail.com
China, Zhejiang, Changxing County; St. Petersburg, 195251
M. Yu. Maksimov
Peter the Great St. Petersburg Polytechnic University
Email: pushnitsa.k@gmail.com
Russian Federation, St. Petersburg, 195251
A. A. Popovich
Peter the Great St. Petersburg Polytechnic University
Email: pushnitsa.k@gmail.com
Russian Federation, St. Petersburg, 195251
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