Study of Structural Changes in LiNi0.8Co0.1Mn0.1O2 Cathode Material for Lithium-Ion Batteries by X-Ray Diffraction Analysis in the In Situ Mode


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Abstract

Structural changes in a promising cathode material LiNi0.8Co0.1Mn0.1O2 for lithium-ion batteries were in situ studied by X-ray diffraction analysis in the course of electrochemical reactions. The Rietveld method and TOPAS 5 software package were used to examine changes in the unit cell parameters of LiNi0.8Co0.1Mn0.1O2 and the reasons for these changes. It was found that the unit cell volume increases by 2% relative to the discharged state (2.7 V) upon charging to 4.2 V.

About the authors

P. A. Novikov

Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute; Peter the Great St. Petersburg Polytechnic University

Email: pushnitsa.k@gmail.com
China, Zhejiang, Changxing County; St. Petersburg, 195251

A. E. Kim

Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute; Peter the Great St. Petersburg Polytechnic University

Author for correspondence.
Email: artem_7.kim@mail.ru
China, Zhejiang, Changxing County; St. Petersburg, 195251

K. A. Pushnitsa

Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute; St. Petersburg State Technological Institute (Technical University)

Author for correspondence.
Email: pushnitsa.k@gmail.com
China, Zhejiang, Changxing County; St. Petersburg, 190013

Wang Quingsheng

Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute; Peter the Great St. Petersburg Polytechnic University

Email: pushnitsa.k@gmail.com
China, Zhejiang, Changxing County; St. Petersburg, 195251

M. Yu. Maksimov

Peter the Great St. Petersburg Polytechnic University

Email: pushnitsa.k@gmail.com
Russian Federation, St. Petersburg, 195251

A. A. Popovich

Peter the Great St. Petersburg Polytechnic University

Email: pushnitsa.k@gmail.com
Russian Federation, St. Petersburg, 195251

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