Hydroprocessing of Vacuum Gas Oil on NiMo Sulfide Catalyst Supported on an Ordered Mesoporous Polymer

E. A. Karakhanov; M. P. Boronoev; E. Yu. Dzhanaeva; I. I. Shakirov; M. V. Terenina; A. L. Maksimov

doi:10.1134/S1070427219020204

Hydroprocessing of Vacuum Gas Oil on NiMo Sulfide Catalyst Supported on an Ordered Mesoporous Polymer

Authors: Karakhanov E.A.¹, Boronoev M.P.¹, Dzhanaeva E.Y.¹, Shakirov I.I.¹, Terenina M.V.¹, Maksimov A.L.¹^,2
Affiliations:
1. Moscow State University
2. Topchiev Institute of Petrochemical Synthesis
Issue: Vol 92, No 2 (2019)
Pages: 300-303
Section: Catalysis
URL: https://journals.rcsi.science/1070-4272/article/view/216366
DOI: https://doi.org/10.1134/S1070427219020204
ID: 216366

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Abstract

The MPF-NiMoS catalyst prepared in situ by decomposition of the thio salt [N(n-Bu)₄]₂[Ni(MoS₄)₂] in pores of an ordered mesoporous phenol-formaldehyde polymer was tested in hydroprocessing of vacuum gas oil in a batch reactor at 380–420°C and a pressure of 5.0 MPa for 5 h. The mean length of sulfide nanoparticles is 4.2 nm, and the mean number of layers is 2. The fraction of lighter products and the degree of desulfurization increase with temperature.