Development of Protective-Layer Catalysts for Removal of Chlorine Compounds from Diesel Fractions


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Abstract

Process of chlorine removal from middle distillates with catalysts based on mesoporous materials was examined. The physicochemical characteristics of supports and catalysts based on SBA-15, Al-TUD, and MCF materials were compared. It was found that the catalyst based on MCF material can diminish the content of chlorine in a light diesel fraction to below 0.3 mg kg–1 at 360°C, pressure of 5.0 MPa, and LHSV of 2.0 h–1.

About the authors

O. V. Golubev

Lomonosov Moscow State University

Author for correspondence.
Email: olegolub@mail.ru
Russian Federation, Moscow, 119991

S. V. Egazar’yants

Lomonosov Moscow State University

Email: olegolub@mail.ru
Russian Federation, Moscow, 119991

D. V. Matevosyan

Lomonosov Moscow State University

Email: olegolub@mail.ru
Russian Federation, Moscow, 119991

E. R. Naranov

Lomonosov Moscow State University; Topchiev Institute of Petrochemical Synthesis

Email: olegolub@mail.ru
Russian Federation, Moscow, 119991; Moscow, 119991

A. L. Maksimov

Lomonosov Moscow State University; Topchiev Institute of Petrochemical Synthesis

Email: olegolub@mail.ru
Russian Federation, Moscow, 119991; Moscow, 119991

E. A. Karakhanov

Lomonosov Moscow State University

Email: olegolub@mail.ru
Russian Federation, Moscow, 119991

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