New Polyampholyte Polymers Based on Polypropylene Glycol Fumarate with Acrylic Acid and Dimethylaminoethyl Methacrylate
- Авторы: Burkeev M.Z.1, Kudaibergen G.K.1, Burkeeva G.K.1, Seilkhanov T.M.2, Tazhbaev E.M.1, Hranicek J.3, Omasheva A.V.1, Davrenbekov S.Z.1
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Учреждения:
- Buketov State University
- Ualikhanov State University
- Karlov University
- Выпуск: Том 91, № 7 (2018)
- Страницы: 1145-1152
- Раздел: Macromolecular Compounds and Polymeric Materials
- URL: https://journals.rcsi.science/1070-4272/article/view/215951
- DOI: https://doi.org/10.1134/S1070427218070121
- ID: 215951
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Аннотация
The possibility of preparing new polyampholyte polymers based on polypropylene glycol fumarate–acrylic acid–dimethylaminoethyl methacrylate terpolymers was demonstrated. The main relationships of radical terpolymerization in dioxane, including binary systems participating in the terpolymerization, were studied. The block lengths, transition probabilities, and Harwood block structure parameter were calculated for the terpolymers from the copolymerization constants for the binary systems. These parameters reflect the arrangement of the macroradicals in the chain. The morphology of the polymer surface was studied by scanning electron microscopy, and the surface pore size was estimated. The influence of organic solvents and pH on the sample swelling was studied, and the isoelectric point (pH 6.00) of the terpolymer was determined.
Об авторах
M. Burkeev
Buketov State University
Email: gulshahar90@mail.ru
Казахстан, Karaganda, 100028
G. Kudaibergen
Buketov State University
Автор, ответственный за переписку.
Email: gulshahar90@mail.ru
Казахстан, Karaganda, 100028
G. Burkeeva
Buketov State University
Email: gulshahar90@mail.ru
Казахстан, Karaganda, 100028
T. Seilkhanov
Ualikhanov State University
Email: gulshahar90@mail.ru
Казахстан, Kokshetau, 020000
E. Tazhbaev
Buketov State University
Email: gulshahar90@mail.ru
Казахстан, Karaganda, 100028
J. Hranicek
Karlov University
Email: gulshahar90@mail.ru
Чехия, Prague
A. Omasheva
Buketov State University
Email: gulshahar90@mail.ru
Казахстан, Karaganda, 100028
S. Davrenbekov
Buketov State University
Email: gulshahar90@mail.ru
Казахстан, Karaganda, 100028
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