Copolymers of N-Methyl-N-vinylacetamide with Allylidene Diacetate
- Authors: Gavrilova I.I.1, Zhuravskaya O.N.1, Panarin E.F.1
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Affiliations:
- Institute of Macromolecular Compounds
- Issue: Vol 91, No 6 (2018)
- Pages: 1025-1028
- Section: Macromolecular Compounds and Polymeric Materials
- URL: https://journals.rcsi.science/1070-4272/article/view/215911
- DOI: https://doi.org/10.1134/S1070427218060228
- ID: 215911
Cite item
Abstract
New random copolymers containing protected aldehyde groups were prepared by radical copolymerization of N-methyl-N-vinylacetamide with allylidene diacetate. The relative activity constants were determined: for N-methyl-N-vinylacetamine, r1 = 1.02 ± 0.015; for allylidene acetate, r2 = 0.95 ± 0.02. Removal of the acetyl protecting groups by base hydrolysis of allylidene diacetate units at 45–50°С yielded water-soluble N-methyl-Nvinylacetamide copolymers with high content of acrolein units, promising for use as polymer carriers of biologically active compounds.
About the authors
I. I. Gavrilova
Institute of Macromolecular Compounds
Email: panarin@hq.macro.ru
Russian Federation, St. Petersburg, 199034
O. N. Zhuravskaya
Institute of Macromolecular Compounds
Email: panarin@hq.macro.ru
Russian Federation, St. Petersburg, 199034
E. F. Panarin
Institute of Macromolecular Compounds
Author for correspondence.
Email: panarin@hq.macro.ru
Russian Federation, St. Petersburg, 199034
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