Radiation-Initiated Synthesis of Tetrafluoroethylene Telomers with Terminal Hydroxy Groups and Controllable Chain Length
- 作者: Kichigina G.A.1, Kushch P.P.1, Kiryukhin D.P.1
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隶属关系:
- Institute of Problems of Chemical Physics
- 期: 卷 91, 编号 6 (2018)
- 页面: 1018-1024
- 栏目: Macromolecular Compounds and Polymeric Materials
- URL: https://journals.rcsi.science/1070-4272/article/view/215910
- DOI: https://doi.org/10.1134/S1070427218060216
- ID: 215910
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详细
Radiation-induced telomerization of tetrafluoroethylene in mixtures of trifluoroethanol and Freon 113 with ethanol at room temperature was studied. Tetrafluoroethylene telomers with different mean chain length and terminal hydroxy groups were obtained. The properties of the telomers were studied by thermal gravimetric analysis, elemental analysis, and IR spectroscopy. The reactive hydroxy groups in the telomers improve the properties of hydrophobic coatings and composites prepared from them owing to enhanced adhesion of the telomeric coating to the support and to formation of chemical bonds with the matrix of fluorine-containing composite materials, in particular, of those based on epoxy resins.
作者简介
G. Kichigina
Institute of Problems of Chemical Physics
编辑信件的主要联系方式.
Email: kga@icp.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
P. Kushch
Institute of Problems of Chemical Physics
Email: kga@icp.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
D. Kiryukhin
Institute of Problems of Chemical Physics
Email: kga@icp.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
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