Conversion of n-Heptane, n-Butane, and Their Mixtures on Catalytic Systems Al2O3/WO42–∙ZrO2 and HMOR/WO42–∙ZrO2


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The conversion of n-C7H16, n-C4H10 and mixtures of C7H16: n-C4H10 = 1: 0.3 on the composite catalysts Al2O3/WO42– ∙ZrO2 (A-WZ) and HMOR/ WO42– ∙ZrO2 (M-WZ) at atmospheric pressure, H2/hydrocarbon = 3 and temperatures of 140-200°C was studied. It was found that a mixture of C7H16: n-C4H10 on M-WZ with high selectivity is converted into C5–C6 isomers. An assumption was made about the mechanism of the formation of the bimolecular intermediate C11, which decays earlier than occurs the formation of the products of the conversion of the mixture C7H16: n-C4H10.

作者简介

S. Abasov

Mamedaliyev’s Institute of Petrochemical Processes

Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

S. Agayeva

Mamedaliyev’s Institute of Petrochemical Processes

Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

M. Mamedova

Mamedaliyev’s Institute of Petrochemical Processes

编辑信件的主要联系方式.
Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

E. Isayeva

Mamedaliyev’s Institute of Petrochemical Processes

Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

A. Imanova

Mamedaliyev’s Institute of Petrochemical Processes

Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

A. Iskenderova

Mamedaliyev’s Institute of Petrochemical Processes

Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

A. Aliyeva

Mamedaliyev’s Institute of Petrochemical Processes

Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

R. Zarbaliyev

Mamedaliyev’s Institute of Petrochemical Processes

Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

D. Tagiyev

Mamedaliyev’s Institute of Petrochemical Processes

Email: memmedova-melahet@mail.ru
阿塞拜疆, Baku, AZ, 1025

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