Mesoporous Zirconium Phosphonate Hybrid Bentonite as a Novel Efficient Catalyst for the Removal of Trace Olefins from Aromatics


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Abstract

A nove l mesoporous zirconium phosphonate hybrid bentonite (MZrPHB ) catalyst was prepared for the removal of trace olefins from refining aromat ic oil. Pyridine-FTIR, NH3‒TPD, XRD, and N2 adsorptiondesorption analysis were applied to characterize acidic properties and textural properties of catalysts. And its olefins removal performance of MZrPHB catalyst was evaluated in comparison with commercial clay catalyst. It is found that the MZrPHB catalyst possesses an abundance of weak Lewis acid centers, large surface area, and regular mesopore, and thus, exhibits a longer treat life and higher olefins conversion compared to commercial clay catalyst. MZrPHB prepared in this report can be considered as a promising and superior alternative material to commercial clays for the purification of aromatics.

About the authors

Mei Wu

Faculty of Chemical Engineering, Huaiyin Institute of Technology; Huai’an Research Center of Chemical and Advanced Materials, Dalian Institute of Chemical Physics

Author for correspondence.
Email: meiwu@hyit.edu.cn
China, Huai’an, 223003; Huai’an, 223005 Jiangsu

Haifeng Han

Jiangsu Hanbon Sci. & Tech, Co., Ltd.

Email: meiwu@hyit.edu.cn
China, Huai’an City, Jiangsu Province

Lingli Ni

Faculty of Chemical Engineering, Huaiyin Institute of Technology

Email: meiwu@hyit.edu.cn
China, Huai’an, 223003

Songlan Zhang

Faculty of Chemical Engineering, Huaiyin Institute of Technology

Email: meiwu@hyit.edu.cn
China, Huai’an, 223003

Shuang Li

Faculty of Chemical Engineering, Huaiyin Institute of Technology

Email: meiwu@hyit.edu.cn
China, Huai’an, 223003

Yuqi Wang

Faculty of Chemical Engineering, Huaiyin Institute of Technology

Email: meiwu@hyit.edu.cn
China, Huai’an, 223003

Jinlong Jiang

Faculty of Chemical Engineering, Huaiyin Institute of Technology

Email: meiwu@hyit.edu.cn
China, Huai’an, 223003

Yichang Pan

State Key Laboratory of Materials-Oriented Chemical Engineering

Email: meiwu@hyit.edu.cn
China, Nanjing, 210009

Jing Chen

Faculty of Chemical Engineering, Huaiyin Institute of Technology

Email: meiwu@hyit.edu.cn
China, Huai’an, 223003

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