Copolymers of 4-Acryloylmorpholine with 2-Dimethyl- and 2-Diethylaminoethyl Methacrylate and Silver-Containing Nanocomposites Based on Them

Yu. I. Zolotova; O. V. Nazarova; T. N. Nekrasova; M. A. Bezrukova; A. V. Melent’ev; A. V. Dobrodumov; E. F. Panarin

doi:10.1134/S1070427218040146

Copolymers of 4-Acryloylmorpholine with 2-Dimethyl- and 2-Diethylaminoethyl Methacrylate and Silver-Containing Nanocomposites Based on Them

Authors: Zolotova Y.I.¹, Nazarova O.V.¹, Nekrasova T.N.¹, Bezrukova M.A.¹, Melent’ev A.V.¹, Dobrodumov A.V.¹, Panarin E.F.¹
Affiliations:
1. Institute of Macromolecular Compounds
Issue: Vol 91, No 4 (2018)
Pages: 623-628
Section: Macromolecular Compounds and Polymeric Materials
URL: https://journals.rcsi.science/1070-4272/article/view/215790
DOI: https://doi.org/10.1134/S1070427218040146
ID: 215790

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Abstract

Copolymers of 4-acryloylmorpholine with 2-dimethyl- and 2-diethylaminoethyl methacrylates of variable composition and molecular mass were prepared by free-radical copolymerization. The reactivity ratios of the comonomers were determined for the first time. The copolymers synthesized are capable to reduce Ag⁺ ions without using additional agents to form stable nanodispersions of zerovalent silver with spherical nanoparticles of 8–10 nm size.