Synthesis of Li-ion Battery Cathode Materials Based on Lithiated Transition Metal Oxides by Spray Method


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Abstract

The parameters of synthesis by the spray method of cathode materials Li1.2Ni0.13Co0.13Mn0.54O2 and Li1.25Ni0.12Co0.12Mn0.51O2, differing in lithium content were studied. The phase and granulometric composition, the morphology of the powder particles obtained, as well as an influence of temperature, total metal concentration, and pH of the solution on the properties of powders of cathode materials were studied. The discharge capacities of the obtained materials reached 260 mAh g‒1 in the range of 2.5‒4.8 V.

About the authors

Qingsheng Wang

Peter the Great St. Petersburg Polytechnic University; Changxing CHN/RUS New Energy and Material Technology Research Institute Co., ltd

Email: novikov.p.a@gmail.com
Russian Federation, ul. Politekhnicheskaya 29/1, St. Petersburg, 195251; Changxing

A. A. Popovich

Peter the Great St. Petersburg Polytechnic University

Email: novikov.p.a@gmail.com
Russian Federation, ul. Politekhnicheskaya 29/1, St. Petersburg, 195251

V. V. Zhdanov

Ioffe Institute

Email: novikov.p.a@gmail.com
Russian Federation, ul. Politechnicheskaya 26, St. Petersburg, 194021

P. A. Novikov

Peter the Great St. Petersburg Polytechnic University

Author for correspondence.
Email: novikov.p.a@gmail.com
Russian Federation, ul. Politekhnicheskaya 29/1, St. Petersburg, 195251

M. Yu. Maximov

Peter the Great St. Petersburg Polytechnic University

Email: novikov.p.a@gmail.com
Russian Federation, ul. Politekhnicheskaya 29/1, St. Petersburg, 195251

Yu. M. Koshtyal

Ioffe Institute

Email: novikov.p.a@gmail.com
Russian Federation, ul. Politechnicheskaya 26, St. Petersburg, 194021

A. M. Rumyantsev

Ioffe Institute

Email: novikov.p.a@gmail.com
Russian Federation, ul. Politechnicheskaya 26, St. Petersburg, 194021

A. O. Silin

Peter the Great St. Petersburg Polytechnic University

Email: novikov.p.a@gmail.com
Russian Federation, ul. Politekhnicheskaya 29/1, St. Petersburg, 195251

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