Email this article In Situ Formation of Al(Fe)/Cl Metal Chloride Complexes and Evaluation of Their Catalytic Properties in the Reaction of Ethylene Oligomerization
- Authors: Arbuzov A.B.1,2,3, Kudrya E.N.1, Trenikhin M.V.1,2,3, Drozdov V.A.1
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Affiliations:
- Institute of Hydrocarbons Processing, Siberian Branch
- Omsk Scientific Center
- Siberian Branch
- Issue: Vol 90, No 12 (2017)
- Pages: 1926-1930
- Section: Catalysis
- URL: https://journals.rcsi.science/1070-4272/article/view/215452
- DOI: https://doi.org/10.1134/S1070427217120059
- ID: 215452
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Abstract
According to FT-IR and UV spectroscopic data, the interaction of the Al/Fe alloy with tert-butyl chloride results in that AlCl4–, Al2Cl7–, and FeCl2+ ion complexes, Fe3+ ions, and AlCl3 molecular form are produced in situ in the reaction medium. Ethylene was oligomerized in n-hexane on metal chloride complexes produced in situ from Al/Fe alloys and tert-butyl chloride.
About the authors
A. B. Arbuzov
Institute of Hydrocarbons Processing, Siberian Branch; Omsk Scientific Center; Siberian Branch
Author for correspondence.
Email: arbuzov1410@mail.ru
Russian Federation, ul. Neftezavodskaya 54, Omsk, 644040; Omsk, 644024
E. N. Kudrya
Institute of Hydrocarbons Processing, Siberian Branch
Email: arbuzov1410@mail.ru
Russian Federation, ul. Neftezavodskaya 54, Omsk, 644040
M. V. Trenikhin
Institute of Hydrocarbons Processing, Siberian Branch; Omsk Scientific Center; Siberian Branch
Email: arbuzov1410@mail.ru
Russian Federation, ul. Neftezavodskaya 54, Omsk, 644040; Omsk, 644024
V. A. Drozdov
Institute of Hydrocarbons Processing, Siberian Branch
Email: arbuzov1410@mail.ru
Russian Federation, ul. Neftezavodskaya 54, Omsk, 644040
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