Association of chitosan in the presence of an anionic surfactant in aqueous-glycerol solutions


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Abstract

The effect of additions of sodium tetradecyl sulfate as an anionic surfactant on the association of chitosan macromolecules in aqueous-glycerol solutions was studied by fluorescence probe spectroscopy and dynamic light scattering. Associates of 40–170 nm size are formed on reaching a certain critical concentration of chitosan in solutions. The critical association concentration of chitosan in solutions containing 10–30 vol % glycerol is higher than in aqueous solutions. Formation of chitosan–surfactant complexes enhances the tendency of chitosan macromolecules to association in water–glycerol mixed solvents.

About the authors

S. V. Shilova

Kazan National Research University of Technology

Author for correspondence.
Email: s_shilova74@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015

A. Ya. Tret’yakova

Kazan National Research University of Technology

Email: s_shilova74@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015

V. P. Barabanov

Kazan National Research University of Technology

Email: s_shilova74@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015

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