Evaluation of the performance of catalysts for joint deep oxidation of hydrocarbons and carbon monoxide under the action of UHF radiation


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Abstract

A series of Сu–Cr–Co/Al2O3/Al catalysts were synthesized under conditions of both traditional heat treatment and action of UHF field, with determination of the thermal transformation properties and degree of radiation penetration into the catalyst bulk. The performance of the catalysts in joint deep oxidation of n-butane and carbon monoxide, stimulated by microwave radiation, was evaluated. The use of the generalized Harrington desirability function reflecting the whole set of definite different-dimension partial responses facilitates the visualization of the expert evaluation of the results and can be recommended for preparing heterogeneous catalysts for related reactions, stimulated by microwave radiation, and for ranking them with respect to performance.

About the authors

P. A. Muradova

Nagiyev Institute of Catalysis and Inorganic Chemistry

Author for correspondence.
Email: kqki@kqki.science.az
Azerbaijan, pr. Dzhavida 113, Baku, AZ1143

S. M. Zul’fugarova

Nagiyev Institute of Catalysis and Inorganic Chemistry

Email: kqki@kqki.science.az
Azerbaijan, pr. Dzhavida 113, Baku, AZ1143

N. V. Shakunova

Nagiyev Institute of Catalysis and Inorganic Chemistry

Email: kqki@kqki.science.az
Azerbaijan, pr. Dzhavida 113, Baku, AZ1143

E. M. Guseinova

Nagiyev Institute of Catalysis and Inorganic Chemistry

Email: kqki@kqki.science.az
Azerbaijan, pr. Dzhavida 113, Baku, AZ1143

A. I. Askerova

Nagiyev Institute of Catalysis and Inorganic Chemistry

Email: kqki@kqki.science.az
Azerbaijan, pr. Dzhavida 113, Baku, AZ1143

Yu. N. Litvishkov

Nagiyev Institute of Catalysis and Inorganic Chemistry

Email: kqki@kqki.science.az
Azerbaijan, pr. Dzhavida 113, Baku, AZ1143

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