Copolymers based on (p-vinylphenyl)cyclopropylmethyl chlorocinnamate and methyl methacrylate
- Authors: Guliyev K.G.1, Aliyeva A.M.1, Ponomareva G.Z.1, Sadygova A.I.1, Mamedli S.B.1, Guliyev A.M.1
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Affiliations:
- Institute of Polymeric Materials
- Issue: Vol 90, No 2 (2017)
- Pages: 262-266
- Section: Macromolecular Compounds and Polymeric Materials
- URL: https://journals.rcsi.science/1070-4272/article/view/214727
- DOI: https://doi.org/10.1134/S1070427217020161
- ID: 214727
Cite item
Abstract
Abstract—Copolymers of (p-vinylphenyl)cyclopropylmethyl chlorocinnamate with methyl methacrylate were prepared by radical copolymerization. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The possibility of photochemical cross-linking of the copolymer via double bond conjugated with the carbonyl group in the chlorocinnamate moiety and via the cyclopropane ring was demonstrated. The copolymer obtained exhibits sufficiently high photosensitivity (54.5 cm2 J–1) and high refractive index (nD20 1.5890), which opens prospects for using it as a photosensitive base of negative photoresists and in optics.
About the authors
K. G. Guliyev
Institute of Polymeric Materials
Author for correspondence.
Email: ipoma@science.az
Azerbaijan, Sumgait, AZ5004
A. M. Aliyeva
Institute of Polymeric Materials
Email: ipoma@science.az
Azerbaijan, Sumgait, AZ5004
G. Z. Ponomareva
Institute of Polymeric Materials
Email: ipoma@science.az
Azerbaijan, Sumgait, AZ5004
A. I. Sadygova
Institute of Polymeric Materials
Email: ipoma@science.az
Azerbaijan, Sumgait, AZ5004
S. B. Mamedli
Institute of Polymeric Materials
Email: ipoma@science.az
Azerbaijan, Sumgait, AZ5004
A. M. Guliyev
Institute of Polymeric Materials
Email: ipoma@science.az
Azerbaijan, Sumgait, AZ5004
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