Effect of sodium dodecyl benzene sulfonate to the displacement performance of hyperbranched polymer

Abstract

Experimental studies were conducted to realize displacement performance effect of anionic surfactant sodium dodecyl benzene sulfonate (SDBS) on hyperbranched poly(AM/AA/AMPS/GA), which was successfully synthesized via free radical polymerization using modified dendritic functional monomer (GA), acrylamide (AM), acrylate (AA), and 2-acrylamido-2-methyl propane sulfonic acid (AMPS). Compared with individual polymer, SP (surfactant polymer) binary systems showed lower apparent viscosity, interfacial tension, and hydrodynamic radius as the result of the electrostatic repulsion between the tail end of hydrophilic polymer branched chain and the head of the surfactant. It was found from abundant static adsorption and dynamic retention tests that the values of static adsorption and dynamics retention of SDBS which is mixed with hyperbranched polymer decrease due to the competitive interaction. However, unlike this phenomenon, SDBS would heighten the dynamic retention value of poly(AM/AA/AMPS/GA), resulting in addition of residual resistance factor. Oil displacement experiment indicated that SP solutions have greater capability of enhance oil recovery than individual polymer under same conditions.