Synthesis and Characterization of Coordination Compounds of 3d-Metal Malonates with Phenylacetyl Hydrazide. Crystal Structure of [Cu(L)2][Cu(Mal)2] · 4.5H2O (L Is Phenylacetyl Hydrazide, Mal2– Is Malonic Acid Anion)


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Three phenylacetyl hydrazide malonate complexes [M(L3)](Mal) of cobalt(II) (I), nickel(II) (II), and zinc(II) (III), as well as complex [Cu(L)2][Cu(Mal)2] ⋅ 4.5H2O (IV) are synthesized. The obtained compounds are characterized by chemical analysis, IR spectroscopy, diffuse reflectance spectroscopy, and thermogravimetry. Compound IV (where L is phenylacetyl hydrazide, and Mal2– is malonic acid anion) is studied by X-ray diffraction analysis (CIF file CCDC no. 1844502).

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V. Sergienko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; All-Russian Institute for Scientific and Technical Information, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: sergienko@igic.ras.ru
俄罗斯联邦, Moscow, 119991; Moscow

T. Koksharova

Mechnikov National University

Email: sergienko@igic.ras.ru
乌克兰, Odessa, 270100

M. Surazhskaya

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: sergienko@igic.ras.ru
俄罗斯联邦, Moscow, 119991

T. Mandzii

Mechnikov National University

Email: sergienko@igic.ras.ru
乌克兰, Odessa, 270100

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