Email this article Synthesis and Characterization of Coordination Compounds of 3d-Metal Malonates with Phenylacetyl Hydrazide. Crystal Structure of [Cu(L)2][Cu(Mal)2] · 4.5H2O (L Is Phenylacetyl Hydrazide, Mal2– Is Malonic Acid Anion)
- Authors: Sergienko V.S.1,2, Koksharova T.V.3, Surazhskaya M.D.1, Mandzii T.V.3
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- All-Russian Institute for Scientific and Technical Information, Russian Academy of Sciences
- Mechnikov National University
- Issue: Vol 45, No 2 (2019)
- Pages: 97-104
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214615
- DOI: https://doi.org/10.1134/S1070328419020076
- ID: 214615
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Abstract
Three phenylacetyl hydrazide malonate complexes [M(L3)](Mal) of cobalt(II) (I), nickel(II) (II), and zinc(II) (III), as well as complex [Cu(L)2][Cu(Mal)2] ⋅ 4.5H2O (IV) are synthesized. The obtained compounds are characterized by chemical analysis, IR spectroscopy, diffuse reflectance spectroscopy, and thermogravimetry. Compound IV (where L is phenylacetyl hydrazide, and Mal2– is malonic acid anion) is studied by X-ray diffraction analysis (CIF file CCDC no. 1844502).
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; All-Russian Institute for Scientific and Technical Information, Russian Academy of Sciences
Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow
T. V. Koksharova
Mechnikov National University
Email: sergienko@igic.ras.ru
Ukraine, Odessa, 270100
M. D. Surazhskaya
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991
T. V. Mandzii
Mechnikov National University
Email: sergienko@igic.ras.ru
Ukraine, Odessa, 270100
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