Crystal Structure of the Polymer Copper(II) Complex with 1-Phenyl-3-Methyl-4-Formyl-5-Hydroxypyrazole Hetarylhydrazone

Yu. P. Tupolova; I. N. Shcherbakov; V. V. Tkachev; L. D. Popov; S. I. Levchenkov; V. A. Chetverikova; G. V. Shilov; S. M. Aldoshin

doi:10.1134/S1070328418020112

Crystal Structure of the Polymer Copper(II) Complex with 1-Phenyl-3-Methyl-4-Formyl-5-Hydroxypyrazole Hetarylhydrazone

Autores: Tupolova Y.P.¹, Shcherbakov I.N.¹, Tkachev V.V.², Popov L.D.¹, Levchenkov S.I.¹^,3, Chetverikova V.A.¹, Shilov G.V.², Aldoshin S.M.²
Afiliações:
1. Southern Federal University
2. Institute of Problems of Chemical Physics
3. Southern Research Center
Edição: Volume 44, Nº 2 (2018)
Páginas: 132-137
Seção: Article
URL: https://journals.rcsi.science/1070-3284/article/view/214388
DOI: https://doi.org/10.1134/S1070328418020112
ID: 214388

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A new coordination polymer of Cu(II) based on 1-phenyl-3-methyl-4-formyl-5-hydroxypyrazole 4,6-dimethylpyrimidylhydrazone is synthesized. The polymer is studied by X-ray diffraction analysis (CIF file CCDC no. 1565772). It is shown that the polymer is formed due to the coordination of the nitrogen atom of the pyrazolone fragment to the copper(II) ion of the adjacent monomeric fragment.