Crystal Structure of the Polymer Copper(II) Complex with 1-Phenyl-3-Methyl-4-Formyl-5-Hydroxypyrazole Hetarylhydrazone


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Abstract

A new coordination polymer of Cu(II) based on 1-phenyl-3-methyl-4-formyl-5-hydroxypyrazole 4,6-dimethylpyrimidylhydrazone is synthesized. The polymer is studied by X-ray diffraction analysis (CIF file CCDC no. 1565772). It is shown that the polymer is formed due to the coordination of the nitrogen atom of the pyrazolone fragment to the copper(II) ion of the adjacent monomeric fragment.

About the authors

Yu. P. Tupolova

Southern Federal University

Email: shcherbakov@sfedu.ru
Russian Federation, Rostov-on-Don

I. N. Shcherbakov

Southern Federal University

Author for correspondence.
Email: shcherbakov@sfedu.ru
Russian Federation, Rostov-on-Don

V. V. Tkachev

Institute of Problems of Chemical Physics

Email: shcherbakov@sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

L. D. Popov

Southern Federal University

Email: shcherbakov@sfedu.ru
Russian Federation, Rostov-on-Don

S. I. Levchenkov

Southern Federal University; Southern Research Center

Email: shcherbakov@sfedu.ru
Russian Federation, Rostov-on-Don; Rostov-on-Don

V. A. Chetverikova

Southern Federal University

Email: shcherbakov@sfedu.ru
Russian Federation, Rostov-on-Don

G. V. Shilov

Institute of Problems of Chemical Physics

Email: shcherbakov@sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

S. M. Aldoshin

Institute of Problems of Chemical Physics

Email: shcherbakov@sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

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