Email this article A New Heterometallic Pb(II)–Ca(II) Coordination Polymer with 2D Pb–O–Ca Inorganic Connectivity
- Authors: An Z.1, Gao J.2, Wang J.3
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Affiliations:
- School of Chemical Engineering, Guangdong University of Petrochemical Technology
- Department of Pharmacy, Mudanjiang Medical University
- School of Environmental and Biological Engineering, Guangdong University of Petrochemical Technology
- Issue: Vol 44, No 12 (2018)
- Pages: 818-823
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214295
- DOI: https://doi.org/10.1134/S1070328418120011
- ID: 214295
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Abstract
A new heterometallic-organic framework, namely [PbCa(Mbdc)2(DMF)]n (I) (H2Mbdc = isophthalic acid, DMF = N,N'-dimethylformamide), was synthesized by the solvothermal reactions of Pb(NO3)2, Ca(NO3)2 · 4H2O and H2Mbdc. Single crystal X-ray diffraction analysis (CIF file CCDC no. 1567197) revealed that compound I features a 3D pillar-layered framework with 2D inorganic Pb–O–Ca connectivity. Thermal analysis indicated that the framework of compound I can be stable up to 320°C, and luminescent property investigation indicated that compound I exhibits intense luminescence at room temperature.
About the authors
Z. An
School of Chemical Engineering, Guangdong University of Petrochemical Technology
Email: zheanngsh@163.com
China,
Maoming, Guangdong Province, 525000
J. Gao
Department of Pharmacy, Mudanjiang Medical University
Email: zheanngsh@163.com
China, Mudanjiang, Heilongjiang Province, 157011
J. Wang
School of Environmental and Biological Engineering, Guangdong University of Petrochemical Technology
Author for correspondence.
Email: zheanngsh@163.com
China, Maoming, Guangdong Province, 525000
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